listview SortColumn property
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Applies to
acListView and acDBListView components.  

property SortColumn: Word;  

The SortColumn property determines and specifies the column number which should be sorted. When SortColumn = 0, first column will be sorted, SortColumn = 1 will sort second column and so forth..  
To specify the sorting direction — use SortDirection property.  

See also
SortDirection and ShowSortMark properties.